Structure-Based Rationale for Selectivity in the Asymmetric Allylic Alkylation of Cycloalkenyl Esters Employing the Trost ‘Standard Ligand’ (TSL): Isolation, Analysis and Alkylation of the Monomeric form of the Cationic 3-Cyclohexenyl Complex [(3-c- C6H9)Pd(TSL)]+
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چکیده
Citation for published version: Butts, CP, Filali, E, Lloyd-jones, GC, Norrby, P, Sale, DA & Schramm, Y 2009, 'Structure-Based Rationale for Selectivity in the Asymmetric Allylic Alkylation of Cycloalkenyl Esters Employing the Trost ‘Standard Ligand’ (TSL): Isolation, Analysis and Alkylation of the Monomeric form of the Cationic 3-Cyclohexenyl Complex [(3-c-C6H9)Pd(TSL)]+' Journal of the American Chemical Society, vol 131, no. 29, pp. 9945–9957. DOI: 10.1021/ja8099757
منابع مشابه
Chiral ferrocene-based phosphine-imine and sulfur-imine ligands for palladium-catalyzed asymmetric allylic alkylation of cycloalkenyl esters
Chiral ferrocene-based phosphine-imine ligands 1–3 and sulfur-imine ligand 4 were applied in the palladium-catalyzed asymmetric allylic alkylation of cycloalkenyl esters. The results revealed that the substitutents in aryl ring, ferrocenylmethyl and benzyliene position strongly affected the enantioselective induction of phosphine-imine ligands, and the most stereoselective ligand was ferrocenyl...
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